One-click electromagnetism at the nanoscale

Silicon nanoparticle Mie resonance calculator

Questions & answers

What is the magnetic dipole resonance of a silicon nanoparticle?

When the wavelength inside the silicon (λ/n, with n ≈ 3.5–4) is about the particle's diameter, the field inside drives a circulating displacement current: a magnetic dipole. It is the lowest-energy Mie resonance of a high-index sphere, at about 467 nm for 100 nm, 580 nm for 140 nm and 770 nm for 200 nm silicon spheres in air (table above), with the electric dipole at shorter wavelengths.

Why are silicon nanoparticles colourful?

Their Mie resonances scatter one band of colours strongly, so in a dark-field microscope or on a surface they shine in vivid structural colours that move from blue (about 100 nm) through green and yellow to red (about 200 nm) as the size grows: no dyes, no plasmons, and almost no absorption.

What is the refractive index of silicon?

About 4.1 at 550 nm, 3.9 at 633 nm and 3.6 at 1000 nm, with absorption that drops steeply from the blue to the near-infrared (band gap 1.12 eV, about 1100 nm). The calculators use the measured data of Green (2008); Aspnes & Studna (1983) is available as an alternative.

Silicon or gold nanoparticles?

Silicon resonances absorb little above about 500 nm, so they scatter efficiently without heating; they support magnetic as well as electric resonances, which allows directional (Kerker) scattering and Huygens metasurfaces. Gold gives stronger near-field enhancement and efficient heating, but with absorption losses.

Can I compute silicon nanospheres, core–shell nanoparticles, arrays, near fields, heating or substrates?

Yes. Silicon is in every calculator: near-field maps (the magnetic-dipole field inside the particle), arrays and lattice resonances, particles on a silicon substrate, emitters near silicon and laser heating.

Scattering, absorption and extinction spectra of silicon nanospheres of any size, with their magnetic and electric dipole resonances, in one click, from exact Mie theory.

Silicon nanoparticle size vs Mie resonances

Silicon spheres in air, from exact Mie theory with this site's solver: the magnetic dipole (MD) and electric dipole (ED) resonances and the colour of the light the particle scatters (as in a dark-field microscope).

DiameterMagnetic dipole (MD)Electric dipole (ED)Qsca at MDAbsorbed share at MDScattering colour
80 nm421 nm390 nm2.561 %
100 nm467 nm410 nm6.034 %
120 nm521 nm441 nm7.820 %
140 nm580 nm477 nm8.713 %
160 nm642 nm519 nm9.29 %
180 nm705 nm564 nm9.46 %
200 nm770 nm611 nm9.64 %
250 nm937 nm734 nm9.91 %

Silicon optical constants: Green (2008), 300 K; in air. MD: the longest-wavelength scattering peak; ED: the next one. Qsca = Csca / πr2. Scattering colour: the scattered spectrum under daylight, normalized in brightness. For larger particles higher-order modes enter the visible and the colour cycles again.

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